Not on this path. It reads the text layer of the DOCX; if that layer is missing - as in a photographed or scanned page - there is nothing to extract. Convert the scan to a searchable document first, then come back for the XLSX.
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The structure is - rows, columns and the values in them. The decoration is not: fills, fonts and borders are not carried into the XLSX, and merged cells are resolved into ordinary ones so the data stays machine-readable.